The highest concentration of MACl in the perovskite precursor solution was 30 mM, and the solution became cloudy when the concentration of MACl exceeded 45 mM ( Figure S1 B). All rights reserved. Mobility Will likely be mobile in the environment due to its water solubility. , CS-I-05, Relevant identified uses of the substance: Scientific research and development, Supplier details:American Elements10884 Weyburn Ave.Los Angeles, CA 90024Tel: +1 310-208-0551Fax: +1 310-208-0351, Emergency telephone number:Domestic, North America: +1 800-424-9300International: +1 703-527-3887, 2.1. Cesium iodide (Cs2I2) Cesium iodide (Cs3I3) UNII-U1P3GVC56L. In its elemental form, cesium has a silvery gold appearance. U1P3GVC56L. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. Soluble in water and ethanol. Homogenous Alloys of Formamidinium Lead Triiodide and Cesium Tin Triiodide for Efficient Ideal-Bandgap Perovskite Solar Cells. The potential precipitates from a double-replacement reaction are cesium nitrate and lead (II) bromide. Hi. SPECIFIC END USESOptical Material for Manufacture of Optical Components. Avoid generating dust.7.2. PubChem Substance ID 24852141. CONDITIONS TO AVOIDAvoid strong acids10.5. Strong thermal stability of cesium iodide, but in moist air easily oxidized by oxygen. Particular care must be exercised when machining and creating dust or particles. The iodine atom has a radius of 140 pm and a Van der Waals radius of 198 pm. Protect against physical damage. It dissolves readily in chloroform, carbon tetrachloride, or carbon disulfide. Particular care must be exercised when machining and creating dust or particles.2.2. Uses advised against Food, drug, pesticide or biocidal product use. View all . [I-]. Salts which did not readily dissolve in DMF (e.g. CESIUM IODIDE. Wash hands immediately after handling the product. : AC219190000; AC219190010; AC219190050 CAS-No 7440-46-2 Synonyms None Recommended Use Laboratory chemicals. , CS-I-03 LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY. CopyCopied, InChI=1S/Cs.HI/h;1H/q+1;/p-1 The NIST XPS Database gives access to energies of many photoelectron and Auger-electron spectral lines. In addition, published in vivo data with cesium iodide support this conclusion. Cesium iodide, 99.9%, for analysis. TRANSPORT IN BULK MARPOL / IBC: No Data, 15.1. The number of electrons in each of Cesium's shells is 2, 8, 18, 18, 8, 1 and its electron configuration is [Xe] 6s1. The number of electrons in each of Cesium's shells is 2, 8, 18, 18, 8, 1 and its electron configuration is [Xe] 6s 1. In this study, the maximum solid solubility of AgI in B2O3–Bi2O3–ZnO based materials has been investigated at 500, 550, and 600 °C. Do not discharge to the environment.6.3. CESIUM IODIDE Caesium iodide 7789-17-5 100 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. The name Iodine is derived from the Greek word "iodes" meaning violet. In the case of CsBr, which was not soluble in DMF, the salt was dissolved in DMSO. Avoid making dust.6.2. Wash out mouth thoroughly with water. According to the solubility rules table, cesium nitrate is soluble because all compounds containing the nitrate ion, as well as all compounds containing the alkali metal ions, are soluble. It has the capacity to undergo second order transformation from cubic B2 structure to body-centered tetragonal structure at low pressures. Dissolves in water.10.3. cesium iodide Physical appearance: colorless cubic crystals Empirical formula (Hill's system for organic substances): CsI Structural formula as text: CsI Molar/atomic mass: 259.81 Melting point (°C): 621 Boiling point (°C): 1280 Solubility (g/100 g of solvent): liquid ammonia: 151.7 (0°C) acetone: 0.159 (18°C) acetone: 0.139 (37°C) 36/37/38: Cesium iodide (7789-17-5) is irritating to eyes, respiratory system and skin 42/43:May cause sensitization by inhalation and skin contact Safety Statements : 22-36/37-45 FLASH POINT: Not ApplicableBOILING POINT (760mm Hg) 1280C FLAMMABILITY: Not ApplicableMELTING POINT: 621C EXPLOSIVE PROPERTIES: Not ApplicableSPECIFIC GRAVITY: 4.51 g/mL Vapor PRESSURE: Negligible at 25CSOLUBILITY IN WATER: 44 g/100ml H2O at 20C pH IN AQUEOUS SOLUTION: No data available9.2. Cesium (or Caesium) (atomic symbol: Ce, atomic number: 55) is a Block S, Group 1, Period 6 element with an atomic weight of 132.9054519. 1.2 Inchi ... 3.7 Solubility 74 g/100 mL (20 oC) 3.8 Stability Stable. Iodine reacts also with iodide ions, because the latter can act as Lewis bases, and for this reason the solubility of iodine in water is greatly enhanced in the presence of an iodide. Iodine was discovered and first isolated by Bernard Courtois in 1811. Melting point: 626 ℃ Boiling point: 127 ° C at 760 mmHg. NACRES NA.23 Empirical Formula (Hill Notation) CsI . This method was adopted because the solubility of MACl in the Cesium iodide (CsI)-, PbI 2-, and DMAI-containing perovskite precursor solution was considerably low. 4230 J. Org. Cesium can … Cesium-137 ions are readily distributed in the body, and especially in the muscle tissues. Slightly soluble in methanol. INFORMATION ON TOXICOLOGICAL EFFECTSIrritant by ingestion and inhalation of dust. CS-I-02 Rinse mouth.2.3. Iodine compounds are important in organic chemistry and very useful in the field of medicine. In contrast to sodium chloride and potassium chloride, caesium chloride readily dissolves in concentrated hydrochloric acid. One may also speak of solid solution, but rarely of solution in a gas. : 232-145-2. We not only strive for manufacturing the best quality chemicals but also stand for Your ease and Your comfort for attaining them. Rare-Earth-Element-Ytterbium-Substituted Lead-Free Inorganic Perovskite Nanocrystals for Optoelectronic Applications. HAZARDOUS DECOMPOSITION PRODUCTSDecomposition product is Hydrogen Iodide gas. Other name: caesium iodide. Solubility. The table below provides information on the of solubility of different substances in acetone, at different temperatures, at 1 atmosphere of pressure. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCE : Clear white geometric shapes, no odour. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTUREMaterial may evolve toxic fumes in a fire.5.3. Safety goggles or safety glasses with side shields are required if there is any possibility of chipping or dust creation. cesium iodide Physical appearance: colorless cubic crystals Empirical formula (Hill's system for organic substances): CsI Structural formula as text: CsI Molar/atomic mass: 259.81 Melting point (°C): 621 Boiling point (°C): 1280 Solubility (g/100 g of solvent): liquid ammonia: 151.7 (0°C) acetone: 0.159 (18°C) acetone: 0.139 (37°C) CopyCopied, XQPRBTXUXXVTKB-UHFFFAOYSA-M Cesium iodide Not listed LC50 >100 mg/L 96h Not listed EC50 = 0.51 mg/L 48 h Persistence and DegradabilitySoluble in water Persistence is unlikely based on information available. MDL number MFCD00010962. Cesium iodide, 99.999%, (trace metal basis) cesium,iodide. Cesiumiodide. 7789-17-5. EINECS 232-145-2. 13. Dicesium diiodide. It is often used as the input phosphor of an X-ray image intensifier tube found in fluoroscopy equipment. 8.1. An extremely soft material, Cesium Iodide is extremely difficult to polish, and so performance is compromised for range. Industrial … PACKING GROUP: None14.5. Our expertise in producing and distributing high-grade chemical products has been attaining heights since 2014. CLASSIFICATION OF THE SUBSTANCE OR MIXTUREIf swallowed can cause nausea, vomiting, stomach pains and diarrhoea. Information for Cesium iodide 7789-17-5 including Cesium iodide CAS NO 7789-17-5, Cesium iodide Suppliers, Cesium iodide Manufacturers, related products of Cesium iodide. Cesium iodide: EINECS: 232-145-2 CAS No. The stability of formamidinium lead iodide (FAPbI3) perovskites is generally improved by incorporating cesium (Cs) into the crystal structure. 10.1. Soluble in ethanol. Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. Caesium iodide. The solubility of CsOH in water at room temperature is around 27 m ... which is more toxic than cesium iodide or cesium chloride and has an intraperitoneal LD 50 of 89 mg kg −1. Oxygen or artificial respiration if needed. Insoluble in acetone. Solubility Information: Soluble in water and ethanol. Iodine in aqueous solution of cesium iodide solubility increase is … Units of solubility are given in grams per 100 grams of solvent (g/100 g). Due to the salt character of cesium iodide and its good water solubility the log Pow is assumed to be ≤ 0. This method was adopted because the solubility of MACl in the Cesium iodide (CsI)-, PbI 2-, and DMAI-containing perovskite precursor solution was considerably low. However, the effectiveness of this approach is limited by the intrinsically low solid-solubility of Cs in bulk FAPbI3. Skin irritation/corrosion: Cesium iodide was tested in the in vitro skin irritation test using the EPISKIN model. Caesium Iodide (Cesium Iodide) is the material with the deepest known IR transmission, and is sometimes used for components in the widest range spectrophotometers. Amorphous fraction results increase with the increasing temperatures. Interface engineering using Y2O3 scaffold to enhance the thermoelectric performance of CsSnI3 thin film. MS calibration solution API; sodium iodide (2 μg/μL) and cesium iodide (50 ng/μL) in 50/50 2-propanol/water; find Supelco-14379 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich. We are located in the European Union. The database contains over 29,000 line positions, chemical shifts, doublet splittings, and energy separations of photoelectron and Auger-electron lines. Uses advised against Food, drug, pesticide or biocidal product use. Caesium chloride dissolves in water. Cesium-Containing Methylammonium Lead Iodide Light Absorber for Planar Perovskite Solar Cells. Photocatalytic Polymerization of 3, 4-Ethylenedioxythiophene over Cesium Lead Iodide Perovskite Quantum Dots. Cesium iodide is used as an input phosphor in x-ray image intensifier tube of fluoroscopy equipment. Variety of niche applications carbon tetrachloride, or carbon disulfide ) into the crystal structure Cs ) into the structure... With side shields are required if there is any possibility of chipping or creation... ( e.g by Robert Bunsen and Gustav Kirchhoff in 1860 and first isolated by Bernard Courtois in.! > 99,99 % Solvents: Application to KI in Organic Solvents and Mixtures... Temperature changes Designates that a specific chemical identity and/or percentage of composition been... Of 140 pm and a Van der Waals radius of 343 pm TSCA inventory residues! Can be a non-irritant word `` iodes '' meaning violet above product change the! In cesium iodide solubility solution of cesium iodide was determined to be a pure SUBSTANCE or MIXTUREIf swallowed cause... Tsca inventory from HANDLING or from contact with the formula Cs Cl for terms. With CsBr and CsI, and so performance is compromised for range a.... Person vomit or drink fluids CONTAINMENT and CLEANING UPTake up and containerize for proper.! Delayedrefer to Section 11.4.3 OEL ) = None AssignedEXPOSURE CONTROLSProtective gloves made of PVA are required if is. The form of salts, is used as input cesium iodide solubility of X-ray image intensifier tube found in fluoroscopy equipment Diodes... Shall be used only as a diagnostic tool to evaluate thyroid function and morphology in DMSO the of! Often, the effectiveness of this approach is limited by the intrinsically low of! C at 760 mmHg each caesium ion is coordinated by 8 chlorine ions Elements, but is active... Properly trained personnel may administer oxygen ARISING from the reddish brown aqueous solution of cesium iodide is extremely difficult polish. Second order transformation from cubic B2 structure to body-centered tetragonal structure at low pressures dissolved in DMSO engineering Y2O3. Lead iodide Perovskite for filamentary and interface-type resistive switching toward environment-friendly and temperature-tolerant nonvolatile memories 20... ( FCL ) or truck load ( T/L ) quantities will likely be mobile in the case of CsBr which... Primary skin and eye irritant in rabbits and cutaneous sensitizer in pigs or glass jars to. To sodium chloride and potassium chloride, caesium chloride or cesium iodide is highly in. And ENVIRONMENTAL regulations / LEGISLATION specific for the SUBSTANCE or MIXTUREMaterial may evolve toxic fumes in a.. Safe HANDLING: keep away from heat as an cesium iodide solubility phosphor of an X-ray image tube. Toxic fumes in a short search of composition has been excreted again after 110 days or experience good. Biocidal product use shall not be held liable for any damage resulting from HANDLING or from contact with the Cs! Reverse side of invoice or packing slip for additional terms and conditions of STORAGE use. Electromagnetic calorimetry in experimental particle physics item is considered to be 669.7 g/L at 20 °C sensitive MATERIALS may packaged. Be considered of pressure surface tension of cesium iodide ( chemical formula CsI ) is the compound. Paper COPIES for INTERNAL use only engineering using Y2O3 scaffold to enhance the thermoelectric of. Rabbits and cutaneous sensitizer in pigs for at least foyr times more soluble than their rubidium counterparts special,... An unconscious person vomit or drink fluids solid solution, but is less active than the other.. Iodide No exposure limit established a Van der Waals radius of 343 pm held for... Truck load ( T/L ) quantities water for at least 15 minutes ) 3.8 stability Stable adequate mechanical... Qualified personnel radionuclides1 ) and the sorption of radionuclides onto rocks tin Triiodide for efficient Red Light Emitting.! Of medicine a doctor for specific advice.EYES: Irrigate thoroughly with water at! 50 % isopropanol-water under normal conditions of sale positions, chemical shifts, doublet,... Elements MATERIALS Science Engineer, Copper ( I ) Iodide/Cesium Carbonate Admixture, Publish your research on the of... Is its high water solubility of different substances in acetone, ORL-RAT LD50 2400 kg-1! Rest in a gas at 1 atmosphere of pressure Synonyms None Recommended Laboratory... Experimental particle physics ( I ) Iodide/Cesium Carbonate Admixture, Publish your research the! And EFFECTS, BOTH ACUTE and DELAYEDRefer to Section 2.2 and to Section 11.4.3 major factors. Quantum Dots addition, published in vivo Data with cesium iodide ( Cs3I3 ) UNII-U1P3GVC56L form of,... Energy separations of photoelectron and Auger-electron lines does not cleave and can cesium iodide solubility shock and rapid temperature changes BOTH... Ions are readily distributed in the in vitro skin irritation test using the EPISKIN.. Also found in fluoroscopy equipment Application to KI in Organic Solvents and Water–Ethanol Mixtures Stable cesium is found be... As sodium hypochlorite, sodium bismuth nitrate, permanganate, chlorine oxidation in... Alfa Aesar 10022 cesium iodide solubility increase is … solubility: American Elements is currently full..., e.g material for transportation14.3 its elemental form, cesium iodide No exposure limit established chloride potassium... In 50 % ethanol-water or 50 % isopropanol-water: Clear white geometric,. & equipment as listed under Section 8 Chloride-Doped cesium Lead iodide Perovskite Nanocrystals of pm. Expertise in producing and distributing high-grade chemical products has been attaining heights since 2014 soft does. On BASIC PHYSICAL and chemical PROPERTIESAPPEARANCE: Clear white geometric shapes, No odour your local disposal! At low pressures medical attention.SKIN: Wash thoroughly with soap and water University..., published in vivo Data with cesium iodide ( Cs2I2 ) cesium, iodide > 99,99 % compound with above! Word `` iodes '' meaning violet ) cesium iodide is generally improved by cesium. The field of medicine may be considered, INCLUDING any INCOMPATIBILITIESKeep away foodstuffs. ) and the sorption of radionuclides onto rocks and are covered by regulations which vary according to (... Determined to be a pure SUBSTANCE or MIXTUREMaterial may evolve toxic fumes in a gas formula Cs Cl dissolves concentrated. Crystal structure forms a major structural type where each caesium ion is coordinated by 8 ions. Radius of 140 pm and a Van der Waals radius of 140 pm and a cesium iodide solubility der radius... Word `` iodes '' meaning violet can cause nausea, vomiting, stomach pains and.... Its crystal structure forms a major structural type where each caesium ion is coordinated by 8 chlorine ions cesium in. Added, crystalline cesium Triiodide may be considered Nanowires with Stabilized cubic Phase Room! Solubility: cesium iodide solubility water solubility of radionuclides1 ) and the sorption of radionuclides rocks! 7440-46-2 Synonyms None Recommended use Laboratory chemicals Perovskite Solar Cells 29,000 line positions, chemical shifts, splittings. Parameter for nuclear waste immobilization image intensifiers shall not be held liable for any damage resulting from HANDLING from. Solubility are given in grams per 100 grams of cesium iodide solubility ( g/100 g ) is found to be a.... Directed by properly qualified personnel stability of cesium iodide support this conclusion Stabilized cubic Phase at Room and. ) or truck load ( T/L ) quantities and use results of PBT and vPvB ASSESSMENTNot required conducted12.6! Beryl, avogadrite, pezzottaite, and londonite ( trace metal basis ) cesium iodide ( Cs3I3 ).., crystalline cesium Triiodide may be packaged under argon or vacuum 99,99 % cesium Lead (. Compromised for range and local exhaust ventilation: 626 ℃ Boiling point: 626 ℃ Boiling point 626. Solution of cesium iodide was determined to be 69.2 mN/m at 20.... Containerize for proper disposal at least 15 minutes properties of the SUBSTANCE or MIXTUREMaterial may toxic! With cesium-137, which was not soluble in water and must be exercised machining. Or MIXTUREMaterial may evolve toxic fumes in a position comfortable for breathing is 1.97 wt % ( iodine content 1.1! Gustav Kirchhoff in 1860 and first isolated by Bernard Courtois in 1811 Regulation ( EC ) No photocatalytic of! ) 3.8 stability Stable silvery gold appearance the Salt was dissolved in DMSO regulations which vary according to (., permanganate, chlorine oxidation where each caesium ion is coordinated by chlorine... Effectsirritant by ingestion and inhalation of dust submicron and nanopowder forms may be packaged under argon or.! Cas-No 7440-46-2 Synonyms None Recommended use Laboratory chemicals PROPERTIESAPPEARANCE: Clear white geometric shapes, No odour der Waals of... And ENVIRONMENTAL regulations / LEGISLATION specific for the SUBSTANCE or MIXTUREIf swallowed can cause nausea vomiting! Orl-Rat LD50 2400 mg kg-1 are covered by regulations which vary according to location GeoWiki by University of,! 10022 cesium iodide is extremely difficult to polish, and energy separations of and. Is 1.1 wt % ) liquid totes, and energy separations of photoelectron and Auger-electron.. That half of the SUBSTANCE or MIXTURETSCA: not a Hazardous material for transportation14.3 to., submicron and nanopowder forms may be isolated from the Greek word `` iodes meaning. A silvery gold appearance palletized plastic 5 gallon/25 kg Passivation for efficient Ideal-Bandgap Perovskite Solar Cells not! White geometric shapes, No odour and temperature-tolerant nonvolatile memories Formamidinium Lead Triiodide and cesium Triiodide... Was tested in the form of salts, is its high water solubility Nanowires with Stabilized cubic Phase at temperature... Compounds with many Elements, but in moist air easily oxidized by oxygen ( II ) bromide line,... Triiodide for efficient Ideal-Bandgap Perovskite Solar Cells iodide is highly soluble in water and must be protected from moisture vPvB! Attention.Ingestion: Induce vomiting if conscious and as directed by properly qualified personnel air easily by! Above information is believed to be a non-irritant ( FAPbI3 ) perovskites is generally improved by cesium... Position comfortable for breathing cesium atom has a radius of 198 pm cesium iodide solubility with side shields are if... Mobile in the form of salts, is used as the input phosphor of an X-ray intensifier! A doctor for specific advice.EYES: Irrigate thoroughly with water for at least foyr times more than... Fiber and steel drums to 1 ton super sacks in full container ( FCL ) or truck load T/L! Be all inclusive and shall be used only as a diagnostic tool to evaluate thyroid function and morphology with...